Michael Owen v Germany - 2002 World Cup Qualifier
Owen bookends the list with a performance to savour against the old enemy away in Germany.
Often regarded as one of the finest England performances of all time, Owen spearheaded a Liverpool inspired 5-1 victory.
Owen levelled after an early German goal as he won a free-kick that he would eventually volley home from.
That was followed by another instinctive finish in the second half before he earned himself the Matchball, notching his third after a pass from teammate Steven Gerrard.
Gerrard and fellow Liverpool forward Emile Heskey completed the rout, a score line that defied expectations and one that was truly made at Anfield.